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Original Articles

Reactions of Oxoanions with Boron Trifluoride

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Pages 523-533 | Received 01 Jul 1974, Accepted 09 Sep 1974, Published online: 13 Dec 2006
 

Abstract

The preparation of salts containing the anions [CrO4(BF3)2]2- [CrO4(BF3)3]2-, [SO4(BF3)2]2- and [SO4(BF3)3]2- is described. Adducts between the oxide ion and BF3 are formed as intermediates in the reaction of BF3 with [NO3], [SO3]2- and [CO3]2- and are decomposed to B2O3 and [BF4].

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