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Original Articles

Pentabromophenyl Derivatives of Gold(I) and Gold(III)

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Pages 17-28 | Received 25 Sep 1974, Accepted 04 Dec 1974, Published online: 05 Dec 2006
 

Abstract

The preparation of (C6Br5)AuPPh3 and that of the complexes X2Au (C6Br5)PPh3 (X = Cl, Br, I), which were obtained by the reaction of the first with halogens, is described.

cis-(C6F5)2Au(C6Br5)PPh 3 was prepared by starting from cis-Cl2 Au(C6Br5)PPh3.

All the complexes are stable at room temperature. They are the first isolated pentabromophenyl derivatives of a transition metal.

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