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Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry Volume 5, 1975 - Issue 2
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Original Articles

The Reaction of the Cyclooctatetraenyl Dianion with Chlorodimethylsilane; Synthesis of Bis-Silylcyclooctatrienes

Jon M. Bellama Department of Chemistry, University of Maryland, College Park, MD, 20742, USA; Department of Inorganic Chemistry, The University, Bristol, BS8 ITS, Great Britain
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John B. Davison Department of Chemistry, University of Maryland, College Park, MD, 20742, USA; Department of Inorganic Chemistry, The University, Bristol, BS8 ITS, Great Britain
Pages 87-94 | Received 30 Oct 1974, Accepted 21 Jan 1975, Published online: 05 Dec 2006
 
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Abstract

Chlorodimethylsilane was reacted with the cyclooctatetraenyl dianion to form a 2:1 mixture of bis-5,8-dimethylsily1-1, 3, 6-cyclooctatriene and bis-7, 8-dimethyl-sily1-1,3,5-cyclooctatriene.

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