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Original Articles

Titanium(IV) Complexes with Schiff Bases

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Pages 439-452 | Received 12 Apr 1978, Accepted 28 Aug 1978, Published online: 05 Dec 2006
 

Abstract

Reactions of titanium isopropoxide with bidentate Schiff bases, such as salicylidene-o-toluidine, salicylidene-p-toluidine, 2-hydroxy-1-naphthylidene-o-toluidine, and 2-hydroxy-1-naphthylidene-p-toluidine in different stoichiometric ratios yield Ti(OPri)4-x (SB)x (where x = 1−3 and SB[sbnd] is the anion of the corresponding Schiff base, SBH) type products. These derivatives have been characterized by elemental analyses, and by infrared spectra and molecular weight determinations.

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