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Original Articles

Synthesis and Characterization of Some Dicyclopenta-dienyl Titanium(IV) Schiff Base Complexes

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Pages 221-242 | Received 27 Jul 1979, Accepted 07 Jan 1980, Published online: 05 Dec 2006
 

Abstract

The equimolar reactions of dicyclopentadienyl titanium(IV) dichloride and bibasic tri- (SBH2) or tetradentate (S'B'H2) Schiff bases have yielded penta-and hexa- coordinated dicyclopentadienyl titanium(IV) Schiff base complexes of the types (C5H5)2Ti(SB) and (C5H5)2Ti(S'B'). These are monomeric in boiling chloroform and on the basis of electronic, infrared, proton magnetic resonance and mass spectral studies, coordination of azomethine nitrogen and phenolic/alcoholic oxygens to titanium atom has been substantiated.

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