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Original Articles

Syntests and Characterization of Scoton of Dinitrois (β-Dinetone) Cobalt (III) Co

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Pages 349-357 | Received 14 Nov 1979, Accepted 07 Feb 1980, Published online: 06 Dec 2006
 

Abstract

A series of new complexes of the cyoe trins Na[co(NC2)2 (AA)2](where RA = 3-dthetone, e.g. acstoacatanilide o-chloroacetoncetanilue, o-acstoacatanilide, o-acstoacat-o-toluioiae, m-acetoacatoxylioide and benzoylacetanll lde have been synthesized and charaeterized on the basts of elemental analysis, magnetic susceptibility measurements, infrared and electronic spectra. The complexes exhibit a band at around 20,000cm-1 due to tha 1A1g→1Tlg transition. The complexes are Gianaygnetic and octanedral. The trans-scrueture has been assignea to the complexes on the basis of tafrared data.

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