Advanced search
Publication Cover
Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry Volume 13, 1983 - Issue 1
Journal homepage
34
Views
19
CrossRef citations to date
0
Altmetric
Original Articles

Reactions of Hydrazinium Hydrazidocarboxylate Salts of Mg, Mn, Fe, Co, Ni and Zn

K. C. Patil Department of Materials Science and Engineering, University of Florida, Gainesville, Florida, 32611; Department of Inorganic and Physical Chemistry, Indian Institute of Science, Bangalore, 560012, India
,
R. Soundararajan Department of Materials Science and Engineering, University of Florida, Gainesville, Florida, 32611; Chemistry Department, S.E. Missouri State University, Cape Girardeau, Missouri, 63701
&
E. P. Goldberg Department of Materials Science and Engineering, University of Florida, Gainesville, Florida, 32611
Pages 29-43 | Received 16 Jun 1982, Accepted 28 Sep 1982, Published online: 05 Dec 2006
 
Sample our Physical Sciences journals, sign in here to start your FREE access for 14 days

Abstract

Magnesium, manganese, iron, cobalt, nickel and zinc salts of hydrazidocarboxylate have been prepared by the reaction of respective metal ions with hydrazinium hydrazidocarboxy late, N2H5COON2H3. Magnesium and manganese form dihydrated salts, M(N2H3COO)2.2H2O. Iron and cobalt form bishydrazine complexes, M(N2H3COO)2(N2H4)2. Nickel and zinc yield N2H5[M(N2H3COO)3].H2O. Infrared spectra and the thermal decomposition of these complexes were investigated.

The iron, cobalt and nickel complexes exhibited autocatalytic decomposition once ignited to yield magnetic oxides. These salts may be of interest as precursors to metal and metal oxide dispersions.

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Order Reprints Request Corporate Permissions

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

Request Academic Permissions

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.

Related Research Data

Solution combustion synthesis of porous β-BaSO 4 nanopowder using benzenesulfonyl methylimidazolium chloride as fuel and sulfonating agent
Source: IOP Publishing
Synthesis and characterization of cobalt(II), nickel(II), copper(II) and zinc(II) complexes of 2-nitrobenzoic acid with methyl carbazate as ancillary ligand. Crystal structure of the copper(II) complex
Source: Springer Science and Business Media LLC

Linking provided by 

Related research

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.