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Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry Volume 13, 1983 - Issue 3
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Original Articles

The Synthesis of 1,1′-Ferrocenyldiamines

Ian R. Butler Department of Chemistry, University of British Columbia 2036 Main Mall Vancouver, B.C. Canada, V6T 1Y6
&
William R. Cullen Department of Chemistry, University of British Columbia 2036 Main Mall Vancouver, B.C. Canada, V6T 1Y6
Pages 321-330 | Received 07 Sep 1982, Accepted 07 Dec 1982, Published online: 05 Dec 2006
 
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Abstract

Symmetrically substituted ferrocenylamine derivatives of the general type Fe(n5−C5H4CH(R)NR′2)2 have been prepared from the ferrocene diol Fe(n5−C5H4CH(R)OH)2 by treatment of the latter with HBr and HNR′2 sequentially. In addition some unsymmetrically substituted ferrocene derivatives such as (n5−C5H4CH:CH2)Fe(n5−C5H4CH(R)NR'2) have been obtained where R=Me.

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