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Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry Volume 13, 1983 - Issue 7
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Original Articles

2,2-Dimethoxyhexamethyltrisilane. A “One-pot” Silicon Atom Synthon

Thomas J. Barton Department of Chemistry, Iowa State University Ames, Iowa, 50011
,
Stephanie A. Burns Department of Chemistry, Iowa State University Ames, Iowa, 50011
,
Peter P. Gaspar Department of Chemistry, Washington University St. Louis, Missouri, 63130
&
Yue-Shen Chen Department of Chemistry, Washington University St. Louis, Missouri, 63130
Pages 881-885 | Received 19 Apr 1983, Accepted 27 May 1983, Published online: 05 Dec 2006
 
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Abstract

Copyrolysis of 2,2-dimethoxyhexamethyltrisilane and 1,3-butadienes affords 5-silaspiro[4.4]nona-2,7-dienes through two cycles of silylene generation and trapping.

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