Cyclometallation, Palladium(II) Complexes with Schiff Base Ligands

J. M. Vila Department of Inorganic Chemistry, Faculty of Chemistry, University of Santiano, Santiago de Compostela, SPAIN

M. T. Pereira Department of Inorganic Chemistry, Faculty of Chemistry, University of Santiano, Santiago de Compostela, SPAIN

A. Suárez Department of Inorganic Chemistry, Faculty of Chemistry, University of Santiano, Santiago de Compostela, SPAIN

E. Gayoso Department of Inorganic Chemistry, Faculty of Chemistry, University of Santiano, Santiago de Compostela, SPAIN

M. Gayoso Department of Inorganic Chemistry, Faculty of Chemistry, University of Santiano, Santiago de Compostela, SPAIN

J. Selbin Department of Inorganic Chemistry, Faculty of Chemistry, University of Santiano, Santiago de Compostela, SPAIN

A. Sen Department of Inorganic Chemistry, Faculty of Chemistry, University of Santiano, Santiago de Compostela, SPAIN

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Abstract

A number of new cyclometallated complexes of palladium with Schiff bases have been synthesized and characterized. These ligands with palladium(II) acetate gave the acetato-bridged dimers. These were converted to the corresponding halooeno-bridged dimers by reaction with sodium chloride or sodium bromide. Reaction of the latter complexes with P(C₆H₅)₃ in a 1:2 molar ratio afforded the cyclometal lated phosphine monomers. All the compounds prepared in this study are characterized by means of IR and ¹H NMD spectroscopy.

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Cyclometallation, Palladium(II) Complexes with Schiff Base Ligands

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Cyclometallation, Palladium(II) Complexes with Schiff Base Ligands

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