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Original Articles

New Synthesis of Acidopentacyanocobaltate(III) Complexes

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Pages 795-800 | Received 09 Aug 1985, Accepted 04 Apr 1986, Published online: 13 Dec 2006
 

Abstract

A new synthetic procedure is described to prepare acidopentacyano-cobaltate (III) complexes: [Co(CN)5X]3- (X = Cl,Br,I,NO2). Salts of [Co(CN)5N3]3- are treated with KNO2 in acid medium in the presence of the coordinating anion X. The compounds were characterized by spectrophotometric and analytical techniques.

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