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Original Articles

Hexafluorophosphate and Oxalate Complexes of 4-Methoxy-2-(5-methoxy-3-methyl-pyrazol-1-yl)-6-methylpyrimidine with Co(II), Ni(II), and Cu(II)

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Pages 821-829 | Received 01 Jan 1986, Accepted 14 Apr 1986, Published online: 13 Dec 2006
 

Abstract

Complexes of Co(II), Ni(II) and Cu(II) with the title ligand, L, have been prepared and characterized through elemental analysis, conductance measurements, electronic and infrared spectra, and magnetic measurements. For all hexafluorophosphate complexes monomeric species with CuL2 2+ and ML3 2+ (M=Co,Ni,Cu) have been isolated. In the oxalate complexes the C2O4 = group act as a bidentate bridge to form compounds with probable dimeric (copper(II)) or polymeric (cobalt(II) and nickel(II)) structures.

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