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Original Articles

Novel Ruthenium(II) Schiff Base Complexes

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Pages 321-337 | Received 26 Aug 1988, Accepted 23 Dec 1988, Published online: 05 Oct 2006
 

Abstract

Schiff bases derived from aromatic aldehydes/ketones and S-benzyldithiocarbazate react with RuHC1 (CO)(PPh3)3 and RuH2(CO)(PPh3)3 to yield [RuX(CO)(PPh3)2(Schiff base] (X = H, C1). The new complexes have been characterised by IR, 1H NMR and UV spectroscopy. The triphenylphosphine ligands in these complexes have been observed to be trans to each other.

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