Di-μ-oxo Complexes of Oxomolybdenum (V) with Carboxylate Ligands

á. L. Doadrio-Villarejo Departamento de Química Inorganica y Bioinorganica. Facultad de Farmacia, Universidad Complutense, 28040, Madrid, Spain

H. T. Calabuig Departamento de Química Inorganica y Bioinorganica. Facultad de Farmacia, Universidad Complutense, 28040, Madrid, Spain

C. V. Ragel Departamento de Química Inorganica y Bioinorganica. Facultad de Farmacia, Universidad Complutense, 28040, Madrid, Spain

A. Doadrio Departamento de Química Inorganica y Bioinorganica. Facultad de Farmacia, Universidad Complutense, 28040, Madrid, Spain

Abstract

We report the synthesis and study of the first examples of oxomolybdenum(V) complexes with μ-dioxo bridges and n-pentyl, n-hexyl, n-heptyl, iso-octyl, cyclohexyl and phenyl carboxylates as ligands. The complexes were characterized by analytical, magnetochemical, IR and visible-U. V. spectral methods and are assigned the formula Mo₂O₄ (RCO₂)₂.

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Di-μ-oxo Complexes of Oxomolybdenum (V) with Carboxylate Ligands

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Di-μ-oxo Complexes of Oxomolybdenum (V) with Carboxylate Ligands

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