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Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry Volume 22, 1992 - Issue 2-3
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Original Articles

Formation of Some Lanthanide(III)/Mercury(II) Heterometallic Complexes by Pyridones

Louisa H. Carrad Chemistry Department, Imperial College of Science, Technology and Medicine, London, SW7 2AY, U. K.
,
David M. L. Goodgamc Chemistry Department, Imperial College of Science, Technology and Medicine, London, SW7 2AY, U. K.
,
Maria Lalia-Kantouri Chemistry Department, Imperial College of Science, Technology and Medicine, London, SW7 2AY, U. K.
&
Graham Winsey Chemistry Department, Imperial College of Science, Technology and Medicine, London, SW7 2AY, U. K.
Pages 269-276 | Received 29 Oct 1991, Accepted 18 Nov 1991, Published online: 22 Nov 2011
 
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Abstract

Reaction of mercury(II) acetate, 2-(lH)-pyridone and hydrated M(NO3)3 (M = Y, Ce, Pr, Nd, Eu, Gd, Dy, or Er) in methanol gave the heterometallic complexes MHg2L4(NO3)3. Use of 4-methyl-2-(lH)-pyridone afforded a similar series of Hg/lanthanide compounds and the complex ThHgL4(NO3)4, and several analogues with 6-methyl-2-(lH)-pyridone and 4-(lH)-pyridone were also isolated.

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