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Original Articles

Synthesis and Characterisation of Novel Binucleating Compounds

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Pages 1789-1803 | Received 25 Aug 1993, Accepted 23 Aug 1994, Published online: 22 Aug 2006
 

Abstract

Novel doubly bidentate Schiff base and bis-carboxyamide ligands were prepared by condensing 4,4′-diaminodiphenyl-sulphone with salicylaldehyde/phenylglyoxal/maleic anhydride. These were then reacted with Cu(II), Co(II), Ni(II) and Fe(II) salts to form their respective complexes. The complexes are dark coloured, high melting substances insoluble in common organic solvents. They have been characterised based on their composition, UV-visible, infrared and ESR spectral data, magnetic susceptibility and thermal studies. In the light of the results obtained, structures of the complexes have been proposed.

Referee I: W. F. Wacholtz

Referee II: K. Moedritzer

Notes

Referee I: W. F. Wacholtz

Referee II: K. Moedritzer

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