Synthesis and Characterization of Some Mixed-Ligand Complexes of Oxovanadium(IV) with Some Aromatic Amines

R. C. Maurya Coordination Chemistry Laboratory, Department of P. G. Studies and Research in Chemistry, R. D. University, Jabalpur, 482 001, India

D. D. Mishra Coordination Chemistry Laboratory, Department of P. G. Studies and Research in Chemistry, R. D. University, Jabalpur, 482 001, India

J. Dubey Coordination Chemistry Laboratory, Department of P. G. Studies and Research in Chemistry, R. D. University, Jabalpur, 482 001, India

Abstract

New mixed-ligand complexes of oxovanadium(IV) of the general formula [VO(C₂O₄)(o-PDA)], where o-PDA = o-phenylenediamine, and [VO(C₂O₄)(L)₂], where L = N-methylaniline (NMA), N,N′-dimethylaniline (NNDMA), N,N′-diethylaniline (NNDEA), o-toluidine (o-TD), m-toluldine (m-TD), o-anisldine (o-ANS), m-anisidine (m-ANS), o-phenetidine (o-PD) or m-phenetidine (m-TD) have been synthesized by refluxing (oxalato) (diaquo)oxovanadium(IV) with the said aromatic amines. The resulting complexes have been characterized on the basis of elemental analyses, vanadium determination, molar conductances, magnetic measurements and infrared spectral studies. Rectangular-pyramidal structures are likely for these complexes.

Referee I: D. H. Williams

Referee II: J. H. Worrell

Notes

Referee I: D. H. Williams

Referee II: J. H. Worrell

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Synthesis and Characterization of Some Mixed-Ligand Complexes of Oxovanadium(IV) with Some Aromatic Amines

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Synthesis and Characterization of Some Mixed-Ligand Complexes of Oxovanadium(IV) with Some Aromatic Amines

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