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Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry Volume 26, 1996 - Issue 5
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Original Articles

Synthesis and Characterization of Copper(I) and Silver(I) Complexes Containing Thioamide Ligands

De-liang Long State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, Nanjing University, Nanjing, 210093, P. R. China
,
Dong-xiang Zeng State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, Nanjing University, Nanjing, 210093, P. R. China
,
Xin-quan Xin State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, Nanjing University, Nanjing, 210093, P. R. China
,
Xiao-ying Huang State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Science, Fuzhou, Fujian, 350002, P. R. China
&
Bei-sheng Kang State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Science, Fuzhou, Fujian, 350002, P. R. China
Pages 723-733 | Received 31 Jul 1995, Accepted 15 Jan 1996, Published online: 21 Aug 2006
 
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Abstract

Mononuclear complexes of the type (Ph3P)2MLX, where M = Cu, Ag; X = Cl, Br; L = dithiooxamide, thiourea. aminothiourea, have been synthesized and characterized by elemental analyses and IR spectra. The X-ray crystallographic structure determination of (Ph3P)2Cu(C2H4N2S2)Br is reported. Dithiooxamide acts as a monodentate ligand through one S atom coordinated to Cu. The coordination of the Cu atom is a distorted tetrahedron with a Cu-Br distance of 2.482(3) and Cu-S distance of 2.356(5) A.

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Related Research Data

Solid-phase synthesis, crystal structure, and quantum chemical calculation of a molybdenum(II) complex with bis(diethyldithiocarbamate)
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