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Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry Volume 28, 1998 - Issue 3
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Original Articles

Synthesis and Magnetic Properties of the First (μ-End-To-End-Azido)Gadolinium(III) Compound: Gd2(phen)4(N3)6(H2O)

Hui-Zhong Kou Department of Chemistry, Nankai University, Tianjin, 300071, P. R. China
,
Dai-Zheng Liao Department of Chemistry, Nankai University, Tianjin, 300071, P. R. China
,
Peng Cheng Department of Chemistry, Nankai University, Tianjin, 300071, P. R. China
,
Zong-Hui Jiang Department of Chemistry, Nankai University, Tianjin, 300071, P. R. China
,
Shi-Ping Yan Department of Chemistry, Nankai University, Tianjin, 300071, P. R. China
&
Geng-Lin Wang Department of Chemistry, Nankai University, Tianjin, 300071, P. R. China
Pages 405-414 | Received 16 Oct 1998, Accepted 28 Oct 1997, Published online: 14 Apr 2008
 
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Abstract

A new Gd(III)-Gd(III) binuclear complex with the formula Gd2(phen)4−(N3)6(H2O) has been synthesized and characterized, where phen is 1,10-phcnanthroline. It has an extended azido-bridged structure consisting of two gadolinium(III) ions in a distorted square antiprismatic environment. The temperature dependence of the magnetic susceptibility of the title complex has been studied resulting in the exchange integral J = −0.23 cm−1 and g = 1.99. This indicates a weak antiferromagnetic interaction between the metal ions.

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