Study of the Coordination Chemistry of Ferrocene-Containing Pywole Derivatives with IIB Group Metal Ions

Hu Ai-Guo Department of Chemistry, National Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin, 300071, P. R. China

Zhang Ling-Yun Department of Chemistry, National Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin, 300071, P. R. China

Fu Nan-Yan Department of Chemistry, National Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin, 300071, P. R. China

Yuan Yao-Feng Department of Chemistry, National Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin, 300071, P. R. China

Ding Ting-Zhen Department of Chemistry, National Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin, 300071, P. R. China

Abstract

Complexes of the type [(3-Fc, 5-Me)Pz]_n'MCl₂ [Fc = ferrocenyl, Pz = pyrazole, M = Zn(II), Cd(II) and n = 1 or 2] have been synthesized and characterized by elemental analyses, IR, ¹H NMR spectra and cyclic voltammetry Elemental analyses reveal a ligand to metal ratio of 1. 1 for Cd(II) and 2 : 1 for Zn(II). No satisfactory elemental analysis results were obtained for the Hg(II) complex due to possible decomposition of the ligand.

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Study of the Coordination Chemistry of Ferrocene-Containing Pywole Derivatives with IIB Group Metal Ions

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Study of the Coordination Chemistry of Ferrocene-Containing Pywole Derivatives with IIB Group Metal Ions

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