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Journal of Coordination Chemistry Volume 50, 2000 - Issue 1
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Original Articles

SYNTHESIS AND STRUCTURE OF A NEW BINUCLEAR CADMIUM(II) CRYPTATE

Xing-You Xu Departments of Chemistry, University of Science and Technology of China, Hefei, 230026, P.R. China; Departments of Chemical Engineering, Huaihai Institute of Technology, Lianyungang, 222005, P.R. China; Departments of Chemistry, University of Science and Technology of China, Hefei, 230026, P.R. China
,
Wei-Xing Ma Departments of Chemical Engineering, Huaihai Institute of Technology, Lianyungang, 222005, P.R. China
,
Hua Chen Departments of Chemical Engineering, Huaihai Institute of Technology, Lianyungang, 222005, P.R. China
,
Wei-Wei Liu Departments of Chemical Engineering, Huaihai Institute of Technology, Lianyungang, 222005, P.R. China
,
Ming-Xing Zhang Departments of Chemical Engineering, Huaihai Institute of Technology, Lianyungang, 222005, P.R. China
,
Qing-Liang Liu Departments of Chemistry, University of Science and Technology of China, Hefei, 230026, P.R. China
&
Zu-De Zhang Departments of Chemistry, University of Science and Technology of China, Hefei, 230026, P.R. China
 show all
Pages 43-50 | Received 14 Apr 1999, Published online: 23 Oct 2006
 
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Abstract

A new binuclear cadmium(II) cryptate has been synthesized by [2+3] Schiff base condensation of tris(3-aminoethyl)amine (tren) with sodium 2,6-diformyl-4-chlorophenolate in the presence of Cd(ClO4)2 · 6H2O. The crystal structure shows that two cadmium(II) ions are bridged by three μ2-phenoxy oxygen atoms. Each cadmium(II) is located in a capped triangular prismatic coordination environment (N4O3).

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Related Research Data

Synthesis, crystal structure, and antibacterial activity of a mononuclear cerium(III) complex derived from tris(2-((5-chlorosalicylidene)amino)ethyl)amine
Source: Informa UK Limited

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