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Journal of Coordination Chemistry Volume 52, 2001 - Issue 3
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Original Articles

THE CRYSTAL AND MOLECULAR STRUCTURE OF A FURAN-2-CARBOXYLATE HETEROBIMETALLIC COMPLEX [Zn(H2O)6]2+[Zn8Na2(C5H3O3)18(OH)2]2-

B. Paluchowska Institute of Atomic Energy, Swierk-Otwock, Poland
,
J. K. Maurin Institute of Atomic Energy, Swierk-Otwock, Poland; Drug Institute, ul. Chełmska 30/34, 00-725, Warszawa
&
J. Leciejewicz Institute of Nuclear Chemistry and Technology, ul. Dorodna 16, 03-195, Warszawa, Poland
Pages 253-264 | Received 02 May 2000, Published online: 22 Sep 2006
 
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Abstract

The crystals of a zinc-sodium complex with furan-2-carboxylate (FCA) as a ligand, n[Zn(H2O)6]2+[Zn8Na2(FCA)18(OH]2]2- n , contain hexahydrated zinc cations and polyanions in which four differently coordinated zinc(II) cations are bridged by bidentate and monodentate (FCA) ligands. In addition, a number of carboxylate and furan ring oxygen atoms are coordinated to sodium(I) atoms which constitute the backbone of the polyanion. [Zn(H2O)6]2+ cations are located in cavities formed by adjacent polyanions and interact with them via a system of hydrogen bonds. The resulting molecular layers are stacked in the crystal along the [100] direction.

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