Advanced search
Publication Cover
Journal of Coordination Chemistry Volume 57, 2004 - Issue 1
Submit an article Journal homepage
49
Views
7
CrossRef citations to date
0
Altmetric
Original Articles

Synthesis, structure and spectroscopy of a copper complex of the chiral pendant-arm macrocycle N,N′,N′′-tris[2S-2-hydroxypropyl]- 1,4,7-triazacyclononane

Wei Han Department of Chemistry, Nankai University, Tianjin 300071, P.R. China
,
Ling Li Department of Chemistry, Nankai University, Tianjin 300071, P.R. China
,
Wen Gu Department of Chemistry, Nankai University, Tianjin 300071, P.R. China
,
Zhan-Quan Liu Department of Chemistry, Nankai University, Tianjin 300071, P.R. China
,
Shi-Ping Yan Department of Chemistry, Nankai University, Tianjin 300071, P.R. China
,
Dai-Zheng Liao Department of Chemistry, Nankai University, Tianjin 300071, P.R. China
,
Zong-Hui Jiang Department of Chemistry, Nankai University, Tianjin 300071, P.R. China
&
Peng Cheng Department of Chemistry, Nankai University, Tianjin 300071, P.R. China
 show all
Pages 41-47 | Accepted 30 Sep 2003, Published online: 20 Aug 2006
 
Sample our Physical Sciences journals, sign in here to start your FREE access for 14 days

Abstract

The preparation, crystal structure and spectroscopy of [Cu(H3L)](ClO4)2] (H3L = N,N′,N′′-tris[2S-hydroxypropyl]-1,4,7-triazacyclononane) is presented. The complex crystallizes in the monoclinic space group P21/c, a = 13.954(5), b = 9.700(4), c = 17.883(7) Å, β = 99.548(8)°, Z = 4; R1 = 0.0665, wR2 = 0.1826. The central copper ion is coordinated to three nitrogen atoms of the macrocycle and three oxygen atoms from the pendant hydroxypropyl groups, forming a distorted octahedral coordination sphere.

Acknowledgements

This work was supported by the NNSF of China (No. 20171026) and the NSF of Tianjin (No. 013605811).

Supplementary Data

Crystallographic data have been deposited with the Cambridge Crystallographic Data Centre, CCDC No. 219829. Copies of this information can be obtained free of charge from The Director, CCDC, 12 Union road, Cambridge, CB2 1EZ, UK (fax: + 44-1223-336-033; email: [email protected] or http://www.ccdc.cam.ac.uk).

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Order Reprints Request Corporate Permissions

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

Request Academic Permissions

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.

Related Research Data

Diastereomeric discrimination in 1,4,7-tris((S )-2-hydroxypropyl)-1,4,7-triazacyclononane and its lithium(I), sodium(I) and zinc(II) complexes
Source: Royal Society of Chemistry (RSC)
Dinuclear Cu(II) complexes based on p -xylylene-bridged bis(1,4,7-triazacyclononane) ligands: Synthesis, characterization, DNA cleavage abilities and evaluation of superoxide dismutase- and catalase-like activities
Source: Wiley
CCDC 219829: Experimental Crystal Structure Determination
Source: Cambridge Crystallographic Data Centre
Synthesis and structural and spectroscopic studies of manganese complexes of pendant-arm macrocycles based on 1,4,7-triazacyclononane: crystal structures of the manganese(II) complex [MnLH3][MnCl4] and of the mixed-valence manganese(II)-manganese(IV) hydrogen-bridged dimer [MnLH3LMn][PF6]3 (LH3 = N,N',N''-tris[(2S)-2-hydroxypropyl]-1,4,7-triazacyclononane) and of the manganese(IV) monomer [MnL'][ClO4] (L'H3 = N,N',N''-tris(2-hydroxyethyl)-1,4,7-triazacyclononane)
Source: American Chemical Society (ACS)
The structures and energy minimization analyses of the macrotricyclic cage complex [Co(nosartacn)]3+ and its precursor [Co(taetacn)]3+
Source: CSIRO Publishing
Synthesis and spectroscopic studies of cobalt(III) complexes of the chiral pendant-arm macrocycle N,N′,N″-tris[(2S)-2-hydroxypropyl]-1,4,7-triazacyclononane (H3L); crystal structure of the hydrogen-bridged dimer [CoLH3LCo][PF6]3
Source: Royal Society of Chemistry (RSC)
Synthesis and crystal structure of zinc-vanadium complex [ZnII(LH3)(L)VIV][PF6]3 [LH3 = N,N',N''-tris(2S)-2-hydroxypropyl-1,4,7-triazacyclononane]: a chiral mixed-metal pendant-arm macrocyclic dimer containing nonvanadyl vanadium(IV)
Source: American Chemical Society (ACS)
Complexes of N,N′,N′′-tris(2-hydroxypropyl)-1,4,7-triazacyclononane (L): Structures of [CuL](ClO4)(NO3), [CoL](ClO4)2, [ZnL](ClO4)2 and the catalytic activity of [MnL](ClO4)2 towards olefin epoxidation with hydrogen peroxide
Source: Springer Science and Business Media LLC
Synthesis, x-ray crystal structure and spectroscopy of the hydrogen-bridged dimer [CrIII(L · H3L)CrIII][PF6]3 (H3L = N,N′,N″-tris[(2S)-2-hydroxypropyl]-1,4,7-triazacyclononane)
Source: Elsevier BV
Improved Richman-Atkins syntheses of cyclic polyamines particularly 1,4,7-Triazacyclononane (tacn) and 1,4,7-Triazacyclodecane (tacd), with the aid of cation-exchange in purification and isolation
Source: CSIRO Publishing

Linking provided by 

Related research

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.