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Journal of Coordination Chemistry Volume 58, 2005 - Issue 17
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Original Articles

Rational synthesis and X-ray structural study of manganese–pyridine–alcohol derivatives

Satoru Onaka Department of Environmental Technology, Graduate School of Engineering, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya 466-8555, JapanCorrespondence[email protected]
,
Li Hong Department of Environmental Technology, Graduate School of Engineering, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya 466-8555, Japan
,
Mitsuhiro Ito Department of Environmental Technology, Graduate School of Engineering, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya 466-8555, Japan
,
Tetsuya Sunahara Department of Environmental Technology, Graduate School of Engineering, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya 466-8555, Japan
,
Hiroyuki Imai Institute for Molecular Science, Myodaiji, Okazaki 444-8484, Japan
&
Katsuya Inoue Institute for Molecular Science, Myodaiji, Okazaki 444-8484, Japan
Pages 1523-1530 | Received 23 Mar 2004, Accepted 10 Feb 2005, Published online: 12 Apr 2011
 
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Abstract

Systematic syntheses of manganese derivatives with 2-pyridineethanol, 2-pyridinemethanol and 2,6-pyridinedimethanol as chelating ligands have been undertaken to produce [trans-Mn(C5H4N-2-CH2CH2OH)2Cl2] (1), [cis-Mn2(μ-Cl)2(Cl)2(C5H4N-2-CH2CH2OH)2(OH2)2] (2), [cis-Mn2(μ-Cl)2(C5H4N-2-CH2OH)4]Cl2 (3) and [MnCl{η3-C5H3N-2,6-(CH2OH)2}{η2-(C5H3N-2,6-(CH2OH)2)}]Cl (4). The complexes were characterized by single-crystal X-ray diffraction. The oxidation state of the manganese ions in these complexes is 2+. Magnetic data are measured down to 2 K; in dimer complexes (2 and 3) a significant antiferromagnetic interaction is observed between two manganese ions.

Acknowledgements

This research was funded by Grants-in-Aid for Scientific Research on Priority Area (No. 12023221 “Metal-assembled Complexes”) and by Grants-in-Aid for Scientific Research (No. 14540514) from the Ministry of Education, Science, Sports and Culture, Japan.

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