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Journal of Coordination Chemistry Volume 58, 2005 - Issue 14
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Original Articles

Synthesis, crystal structure and magnetic property of a maleonitriledithiolate nickel(III) complex containing an ammonium crown ether cation

Li-Li Wen Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, 210093, P.R. China
,
Chun-Lin Ni Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, 210093, P.R. China
,
Dong-Bin Dang Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, 210093, P.R. China
,
Yi-Zhi Li Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, 210093, P.R. China
,
Yan-Ping Wu Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, 210093, P.R. China
,
Qing-Jin Meng Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, 210093, P.R. ChinaCorrespondence[email protected]
&
Song Gao State Key Laboratory of Rare Earth Materials Chemistry and Applications, Peking University, Beijing, 100871, P.R. China
 show all
Pages 1209-1215 | Accepted 18 Jan 2005, Published online: 25 Jan 2007
 
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Abstract

The synthesis, molecular structure and spectroscopic and magnetic properties of (NH4)2(15-crown-5)3[Ni(mnt)2]2 (mnt = maleonitriledithiolate dianion) are reported. The most notable structural feature of (NH4)2(15-crown-5)3[Ni(mnt)2]2 is that the ions form a stacked structure with well-separated columns along the c and a axes. Variable temperature magnetic susceptibility measurements indicate strong antiferromagnetic interactions in the complex.

Acknowledgements

We thank the National Nature Science Foundation of China (20171022, 20490210), the Jiangsu Science and Technology Department and the Centre for Analysis of Nanjing University for financial support.

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