Advanced search
Publication Cover
Journal of Coordination Chemistry Volume 58, 2005 - Issue 17
Submit an article Journal homepage
77
Views
3
CrossRef citations to date
0
Altmetric
Original Articles

Studies of η5-cyclichydrocarbon ruthenium(II) complexes containing para-amino-N-(pyrid-2-ylmethylene)phenylamine ligand: molecular structure of [(η5-C5H5)Ru(PPh3)(C5H4NCH=N-C6H4-p-NH2)]BF4

Keisham Sarjit Singh Department of Chemistry, North-Eastern Hill University, Shillong 793022, India
,
Glenn P. A. Yap 201 Brown Laboratory, Department of Chemistry and Biochemistry, University of Delaware, Netwark, Delaware, USA
,
K. A. Kreisel 201 Brown Laboratory, Department of Chemistry and Biochemistry, University of Delaware, Netwark, Delaware, USA
&
Mohan Rao Kollipara Department of Chemistry, North-Eastern Hill University, Shillong 793022, IndiaCorrespondence[email protected]
Pages 1607-1613 | Accepted 01 May 2003, Published online: 12 Apr 2011
 
Sample our Physical Sciences journals, sign in here to start your FREE access for 14 days

Abstract

Reaction of [(η5-Cp)Ru(PPh3)2Cl] (1) with excess para-amino-N-(pyrid-2-ylmethylene)-phenylamine ligand (app) in methanol in the presence of NH4BF4 leads to the formation of [η5-CpRu(PPh3)(aap)]BF4 (6BF4). Similarly, [(η5-ind)Ru(PPh3)2(CH3CN)]BF4 (4BF4) and [(η5-Cp*)Ru(PPh3)2(CH3CN)]BF4 (5BF4) react with app to yield the cationic complexes [(η5-ind)Ru(PPh3)(app)]BF4 (7BF4) and [(η5-Cp*)Ru(PPh3)(app)]BF4 (8BF4), respectively. The complexes were characterized by analysis and spectroscopic data. The structure of a representative complex (6BF4) was established by single-crystal X-ray methods.

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Order Reprints Request Corporate Permissions

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

Request Academic Permissions

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.

Related Research Data

Chemistry of the Cyciopentadienyl Bisphosphine Ruthenium Auxiliary
Source: Elsevier
Electron-rich cations: preparation and hydride reductions of the salts {(.eta.5-C5H5)Ru[MeC(CH2PPh2)3]}PF6 and {(.eta.5-C5H5)Ru[PhP(CH2CH2PPh2)2]}PF6
Source: American Chemical Society (ACS)
Cyclopentadienyl-ruthenium and -osmium Chemistry. VII. Complexes Containing Nitriles, Tertiary Phosphines or Phosphites Formed by Addition or Displacement Reactions
Source: CSIRO Publishing
Syntheses and characterization of indenylruthenium(II) complexes containing N,N′ donor Schiff base ligands. Molecular structures of [(η5-C9H7)Ru(PPh3)2(CH3CN)]BF4 and [(η5-C9H7)Ru(PPh3)(C5H4–N-2–CHN–C6H4-p-CH3)]BF4
Source: Elsevier BV
Indenyl complexes of ruthenium(II). Crystal structure of [Ru(CO)(PPh3)2(η5-C9H7)]ClO4·CH2Cl2
Source: Elsevier BV
Cyclopentadienyl-ruthenium and -osmium chemistry. IV. Convenient high-yield synthesis of some cyclopentadienyl ruthenium or osmium tertiary phosphine halide complexes
Source: CSIRO Publishing
Chemoselectivity in the ruthenium-catalyzed redox isomerization of allyl alcohols
Source: American Chemical Society (ACS)
Reactivity studies of cyclopentadienyl bis(triphenylphosphine)ruthenium(II) complex towards some polypyridyl ligands
Source: Elsevier BV
The use of conductivity measurements in organic solvents for the characterisation of coordination compounds
Source: Elsevier BV
CCDC 270849: Experimental Crystal Structure Determination
Source: Cambridge Crystallographic Data Centre
Cyclopentadienylruthenium complexes with chelating diamines and diolefins. Crystal structures of [Ru(nbd)(PPh3)(ϑ-C5H5)]ClO4 and [Ru{(η6-C6H5)Ph2PO}(η-C5H5)]ClO4. A new mode of coordination of triphenylphosphine oxide
Source: Elsevier BV
Reactivity and X-ray Structural Studies in Ligand Substitution of [Cp/(Ind)Ru(dppf)Cl] – Epimerisation in [Cp/(Ind)Ru(Josiphos)Cl] {Cp = η5-C5H5, Ind = η5-C7H9, dppf = 1,1′-Bis(diphenylphosphanyl)ferrocene, Josiphos = (R)-(–)-1-[(S)-2-(Diphenylphosphanyl)ferrocenyl]ethyldicyclohexylphosphane}
Source: Wiley
Crystal Structure and Spectroscopic Characterization of Zinc(II) and Mercury(II) Complexes of -(Pyridin-2-ylmethylene)benzene-1,4-diamine
Source: (:unav)
Ruthenium-catalyzed addition of alkenes to acetylenes
Source: American Chemical Society (ACS)
Pentamethylcyclopentadienyl ruthenium(II) complexes of para-substituted N-(pyrid-2-ylmethylene)-phenylamine ligands: syntheses, spectral and structural studies
Source: Elsevier BV
Preparation and reactions of some neutral pentamethylcyclopentadienylruthenium vinylidene complexes
Source: Royal Society of Chemistry (RSC)
Flexible coordination of indenyl ligands in sandwich complexes of transition metals. Molecular structures of [(η-C9R7)2M] (M = Fe, R = H, Me; M = Co, Ni, R = H): Direct measurement of the degree of slip-fold distortion as a function of d-electron count
Source: Elsevier BV
Cyclopentadienyl-ruthenium and -osmium chemistry. Part 11. Reactions and structures of [RuCl(PPh3)2(η-C5H5)] and its trimethyl-phosphine analogue
Source: Royal Society of Chemistry (RSC)
(Indenyl)ruthenium Complexes Containing 1,1′-Bis(diphenylphosphanyl)ferrocene (dppf) and Thiolato Ligands: Synthesis, X-ray Structure Analysis, Electrochemistry and Magnetic Studies
Source: Wiley
Density‐functional thermochemistry. III. The role of exact exchange
Source: AIP Publishing

Linking provided by 

Related research

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.