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Journal of Coordination Chemistry Volume 61, 2008 - Issue 5
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Original Articles

Hydrothermal synthesis, structure and properties of a heteronuclear Co(III)–Ag(I) complex with the 2,6-pyridine-dicarboxlate

Qingjin Sun Department of Chemistry, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, Northwest University, Xi’an, Shaanxi 710069, China
,
Quanchang Gao Department of Chemistry, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, Northwest University, Xi’an, Shaanxi 710069, China
,
Weiping Zhang Department of Chemistry, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, Northwest University, Xi’an, Shaanxi 710069, China
,
Yanhong Song Department of Chemistry, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, Northwest University, Xi’an, Shaanxi 710069, China
,
Zhanwei Xu Department of Chemistry, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, Northwest University, Xi’an, Shaanxi 710069, China
,
Biyun Su Department of Chemistry, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, Northwest University, Xi’an, Shaanxi 710069, China
&
Jianshe Zhao Department of Chemistry, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, Northwest University, Xi’an, Shaanxi 710069, ChinaCorrespondence[email protected]
 show all
Pages 669-676 | Received 26 Mar 2007, Accepted 21 Apr 2007, Published online: 03 Mar 2008
 
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Abstract

A new Ag/Co coordination polymer, [AgCo(PDC)2] (1) (H2PDC = 2,6-pyridine-dicarboxylic acid) was synthesized under hydrothermal condition. X-ray crystallographic study reveals that 1 is a 2D network and has a previously unexplored coordination mode. Solid state fluorescence and thermogravimetric analysis (TGA) have been performed.

Acknowledgements

We are grateful to the Natural Science Foundation of China (No. 20671076), the National Basic Research Program (the 973 Program, No. 2003CB214600), the Program for Changjiang Scholars and Innovative Research Team in University, PCSIRT (IRT0559), the Key Laboratory Research and Establishment Program of Shaanxi Education Section (No. 03JS006) for financial support.

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