Advanced search
Publication Cover
Journal of Coordination Chemistry Volume 61, 2008 - Issue 14
Submit an article Journal homepage
35
Views
2
CrossRef citations to date
0
Altmetric
Original Articles

Spectroscopic, thermal and structural studies of a new mercury(II) one-dimensional coordination polymer, [Hg(3-bpo)2(SCN)2], 3-bpo = 2,5-bis(3-pyridyl)-1,3,4-oxadiazole

Mohammad Jafar Soltanian Fard-Jahromi Faculty of Basic Science, Department of Chemistry, Science and Research Campus, Islamic Azad University, Tehran, Iran
,
Ali Morsali Faculty of Sciences, Department of Chemistry, Tarbiat Modares University, Tehran, IranCorrespondence[email protected]
&
Matthias Zeller Department of Chemistry, Youngstown State University, One University Plaza, Youngstown, Ohio, USA
Pages 2227-2233 | Received 10 Jun 2007, Accepted 20 Jul 2007, Published online: 01 Jul 2008
 
Sample our Physical Sciences journals, sign in here to start your FREE access for 14 days

Abstract

A new mercury(II)-organic polymeric complex generated from 2,5-bis(3-pyridyl)-1,3,4-oxadiazole (3-bpo) as an angular dipyridyl derivative ligand, [Hg(3-bpo)2(SCN)2], was prepared from reactions of ligand 3-bpo with mercury(II) thiocyanate. The compound was characterized by elemental analysis, IR-, 1H NMR-, 13C NMR-spectroscopy and structurally determined by X-ray single crystal diffraction. The thermal stability of [Hg(3-bpo)2(SCN)2] was studied by thermal gravimetric (TG) and differential thermal analyses (DTA).

Acknowledgement

Support of this investigation by the Science and Research Campus of Islamic Azad University is gratefully acknowledged.

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Order Reprints Request Corporate Permissions

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

Request Academic Permissions

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.

Related Research Data

Synthesis and characterization of new coordination polymers generated from oxadiazole-containing organic ligands and inorganic silver(I) salts.
Source: American Chemical Society (ACS)
Recent Advances in Luminescent Monomeric, Multinuclear, and Polymeric Zn(II) and Cd(II) Coordination Complexes
Source: CSIRO Publishing
Funktionale poröse Koordinationspolymere
Source: Wiley
A titanosilicate molecular sieve with adjustable pores for size-selective adsorption of molecules
Source: Springer Science and Business Media LLC
Engineering coordination polymers towards applications
Source: Royal Society of Chemistry (RSC)
Self-Assembly of Nanometer-Scale Secondary Building Units into an Undulating Two-Dimensional Network with Two Types of Hydrophobic Cavity
Source: Wiley
New two-dimensional metal-organic networks constructed from 1,2,4,5-benzenetetracarboxylate and chelate ligands.
Source: American Chemical Society (ACS)
POLYCATENATION, POLYTHREADING AND POLYKNOTTING IN COORDINATION NETWORK CHEMISTRY
Source: Elsevier BV
Two Interpenetrating 3D Networks Which Generate Spacious Sealed-Off Compartments Enclosing of the Order of 20 Solvent Molecules in the Structures of Zn(CN)(NO3)(tpt)2/3.cntdot.solv (tpt = 2,4,6-tri(4-pyridyl)-1,3,5-triazine, solv = .apprx.3/4C2H2Cl4.cntdot.3/4CH3OH or .apprx.3/2CHCl3.cntdot.1/3CH3OH)
Source: American Chemical Society (ACS)
Crystal structure and spectroscopic study of novel two- and three-dimensional photoluminescent Eu(III)-adipate compounds.
Source: American Chemical Society (ACS)
A unique eclipsed 2-D coordination polymer with removable iodine molecules in the open-channel structure
Source: Royal Society of Chemistry (RSC)
Polygons and Faceted Polyhedra and Nanoporous Networks.
Source: Wiley
Metal-organic frameworks
Source: Royal Society of Chemistry (RSC)
Self-Assembly of Nanometer-Scale Secondary Building Units into an Undulating Two-Dimensional Network with Two Types of Hydrophobic Cavity
Source: Wiley
From metallacyclophanes to 1-D coordination polymers: role of anions in self-assembly processes of copper(II) and 2,5-bis(3-pyridyl)-1,3,4-oxadiazole.
Source: American Chemical Society (ACS)
One-dimensional coordination polymers generated from an oxadiazole-containing N,N′-bipyridine-type ligand and inorganic salts
Source: Elsevier BV
Synthesis and characterisation of infinite co-ordination networks from flexible dipyridyl ligands and cadmium salts
Source: Royal Society of Chemistry (RSC)
Bis[aqua(2,5-bis(4-pyridyl)-1,3,4-oxadiazole)thiocyanate] cadmium(II): A three-dimensional framework built from hydrogen bonds and π-π stacking interactions
Source: (:unav)
Synthesis and characterization of new coordination polymers generated from oxadiazole-containing ligand and inorganic M(II) [M = Cu(II), Co(II)] salts
Source: Royal Society of Chemistry (RSC)
[CdII(bpdc).H2O]n: A robust, thermally stable porous framework through a combination of a 2-D grid and a cadmium dicarboxylate cluster chain (H2bpdc = 2,2'-bipyridyl-4,4'-dicarboxylic acid)
Source: (:unav)
(4,4'-bipyridine)mercury(II) coordination polymers, syntheses, and structures
Source: Wiley
Structure and magnetism of coordination polymers containing dicyanamide and tricyanomethanide
Source: Elsevier BV
Synthesis and characterization of new coordination polymers generated from oxadiazole-containing ligands and IIB metal ions
Source: Elsevier BV
Quantitative Formation of Coordination Nanotubes Templated by Rodlike Guests
Source: American Chemical Society (ACS)
Self-assembly of coordination polymers from AgX (X = SbF(6)(-), PF(6)(-), and CF(3)SO(3)(-)) and oxadiazole-containing ligands.
Source: (:unav)
A new synthesis of symmetrical 2,5‐disubstituted 1,3,4‐oxadiazoles
Source: Wiley
Coordination polymers assembled from angular dipyridyl ligands and CuII, CdII, CoII salts: crystal structures and properties.
Source: (:unav)
A novel one-dimensional helical chain polymer involving both tetra- and hexacoordinate mercury(II) ions
Source: Elsevier BV
[M(L)2(NCS)2(H2O)2] (M=MnII or CoII and L=2,5-bis(4-pyridyl)-1,3,4-oxadiazole): three-dimensional extended networks built from hydrogen bonds and π–π stacking interaction—syntheses and crystal structures
Source: Elsevier BV
CCDC 644399: Experimental Crystal Structure Determination
Source: Cambridge Crystallographic Data Centre
A Novel One‐Dimensional Coordination Polymer Involving Weak Hg ? Hg Interactions
Source: Wiley
Synthetic Strategies, Structure Patterns, and Emerging Properties in the Chemistry of Modular Porous Solids†
Source: American Chemical Society (ACS)
Magnetic Nanoporous Coordination Polymers
Source: Wiley
Organic-Inorganic Hybrid Materials: From "Simple" Coordination Polymers to Organodiamine-Templated Molybdenum Oxides.
Source: Wiley

Linking provided by 

Related research

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.