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Journal of Coordination Chemistry Volume 61, 2008 - Issue 14
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Original Articles

Syntheses, structures and properties of two complexes bridged by [M(CN)2]− (M = Ag (I), Au (I))

Mei-Ling Liu Department of Chemistry, Nankai University, Weijin Road, Tianjin 300071, P.R. China
,
Li-Zhi Zhang Department of Chemistry, Nankai University, Weijin Road, Tianjin 300071, P.R. China
,
Xiu-Ping Sun Department of Chemistry, Nankai University, Weijin Road, Tianjin 300071, P.R. China
,
Zhen-Ping Ma Department of Chemistry, Nankai University, Weijin Road, Tianjin 300071, P.R. China
,
Wen Gu Department of Chemistry, Nankai University, Weijin Road, Tianjin 300071, P.R. China
&
Xin Liu Department of Chemistry, Nankai University, Weijin Road, Tianjin 300071, P.R. ChinaCorrespondence[email protected]
Pages 2266-2273 | Received 14 Jun 2007, Accepted 18 Oct 2007, Published online: 01 Jul 2008
 
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Abstract

A dinuclear complex Cu2(bpca)2(H2O)2(Ag2(CN)3) (1) and a 1D complex [Cu2(bpca)2(H2O)2(Au(CN)2)2] n (2) (bpca = bis(2-pyridylcarbonyl)amide anion) have been prepared, structurally characterized and 2 has been magnetically characterized. The magnetic properties show an antiferromagnetic interaction between the two Cu(II) ions. Based on the Hamiltonian Ĥ = −2J Σ (Si · Si +1), best fitting for the experimental data leads to J = −0.045 cm−1.

Acknowledgements

This work was supported by the National Natural Science Foundation of China (Grant 20371027 and 20071020) and Tianjin Science Foundation (Grant 033609211).

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