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Journal of Coordination Chemistry Volume 61, 2008 - Issue 20
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Original Articles

Crystal structure and thermal decomposition kinetics of a 2D coordination polymer of cadmium(II)

Ying-Xia Zhou College of Science, Henan Agricultural University, Zhengzhou 450002, ChinaCorrespondence[email protected]
,
Si-Yin Liu Department of Chemistry, Shangqiu Normal College, Shangqiu 476000, China
,
Xiao-Qing Shen Department of Chemistry, Zhengzhou University, Zhengzhou 450052, China
,
Hong-Yun Zhang Department of Chemistry, Zhengzhou University, Zhengzhou 450052, China
&
Ya-Hui Yu Department of Chemistry, Zhengzhou University, Zhengzhou 450052, China
Pages 3237-3244 | Received 15 Jun 2007, Accepted 04 Aug 2007, Published online: 13 Oct 2008
 
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Abstract

A 2D cadmium(II) coordination polymer with oxalate and 2,2′-bipyridine, [Cd2(bpy)(ox)2(H2O)2] n · nH2O, was synthesized and the single crystal structure was determined by X-ray crystallography. Thermal properties and the decomposition kinetics of the title complex were studied showing that the decomposition of this complex in N2 is a two-step process, A . Kinetic parameters were obtained.

Acknowledgement

This work was financially supported by the National Science Foundation of China (20501017).

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