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Journal of Coordination Chemistry Volume 61, 2008 - Issue 20
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Original Articles

Synthesis, structure and nonlinear optical properties of three dimensional compounds

Zhao Rui Pan Coordination Chemistry Institute and the State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, People's Republic of China
,
You Cai Zhang Coordination Chemistry Institute and the State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, People's Republic of China
,
Ying Lin Song Department of Physics, Suzhou University, Suzhou 215006, People's Republic of China
,
Xin Zhuo Suzhou College, The Photoelectric Chemistry Laboratory, Suzhou 234000, People's Republic of China
,
Yi Zhi Li Coordination Chemistry Institute and the State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, People's Republic of China
&
He Gen Zheng Coordination Chemistry Institute and the State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, People's Republic of ChinaCorrespondence[email protected]
Pages 3189-3199 | Received 09 Jul 2007, Accepted 04 Sep 2007, Published online: 13 Oct 2008
 
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Abstract

The combination of metal ions with H3tbba has resulted in the formation of two three dimensional coordination compounds {[Zn(H2tbba)2(H2O)] · 2(OC3H6)} n (1) and {[Mn(H2tbba)2(H2O)] · 2(OC3H6)} n (2) (H2tbba = 2-thiobarbituric acid anion). Compounds 1 and 2 are isostructural with metal ions bridged by four hydroxyl oxygens from four different H2tbba ligands to form a 3D network. H2tbba exhibits bidentate coordination with both hydroxyl oxygens participating in coordination, a new coordination mode. Nonlinear absorption and refraction of 1 and 2 in DMF are studied by using Z-scan measurement technique at 532 nm. 1 and 2 possess nonlinear optical absorption and self-focusing.

Acknowledgements

We thank the National Natural Science Foundation of China (Nos. 20571039 and 20171020), the Ministry of Education of China (No. 20050284031) and the Natural Science Foundation of Jiangsu province (No. BK2006124).

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