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Journal of Coordination Chemistry Volume 61, 2008 - Issue 20
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Original Articles

Solvent-controlled synthesis and crystal structures of a pair of azido-bridged copper(II) complexes constructed from 1-[(3-dimethylaminopropylimino)methyl]naphthalen-2-ol

Zhong-Lu You Department of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian 116029, P.R. ChinaCorrespondence[email protected]
,
Xiao-li Ma Department of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian 116029, P.R. China
&
Shu-Yun Niu Department of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian 116029, P.R. China
Pages 3297-3305 | Received 04 Sep 2007, Accepted 08 Jan 2008, Published online: 13 Oct 2008
 
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Abstract

A pair of azido-bridged copper(II) complexes, [Cu2L2(μ 1,1-N3)2] (1) and [Cu2L2(μ 1,3-N3)2] · H2O (2) (HL = 1-[(3-dimethylaminopropylimino)methyl]naphthalen-2-ol), have been obtained from an identical synthetic procedure and starting materials with solvents as the only independent variable. Complex 1 was synthesized and crystallized using the anhydrous methanol, while 2 was synthesized and crystallized using 95% ethanol. Both complexes show interesting self-assembled structures in their crystals as elucidated by X-ray analysis. The end-on azido-bridged dinuclear 1 crystallizes in the P 1 space group. The end-to-end azido–bridged polymeric 2 crystallizes in the P21/c space group.

Acknowledgements

This work was financially supported by the Office of Dalian Science & Technology (Project No. 2007J23JH018) and by the Scientific Research Foundation of the Education Office of Liaoning Province (Project No. 20060495).

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