Advanced search
Publication Cover
Journal of Coordination Chemistry Volume 61, 2008 - Issue 20
Submit an article Journal homepage
53
Views
5
CrossRef citations to date
0
Altmetric
Original Articles

Hydrothermal syntheses and crystal structures of new uranyl complexes: UO2(p-C7H4O2Br)2(H2O) and UO2(m-C7H4O2Br)2

Cai Yige Department of Chemistry, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, Northwest University, Xi’an, 710069, China
,
Zhang Weihai Department of Chemistry, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, Northwest University, Xi’an, 710069, China
,
Sun Qingjin Department of Chemistry, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, Northwest University, Xi’an, 710069, China
,
Zhang Weiping Department of Chemistry, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, Northwest University, Xi’an, 710069, China
,
Zhao Jianshe Department of Chemistry, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, Northwest University, Xi’an, 710069, ChinaCorrespondence[email protected]
,
Miao Jianyu Department of Geology, Northwest University, Xi’an 710069, China
,
Ren Zhanli Department of Geology, Northwest University, Xi’an 710069, China
&
Liu Chiyang Department of Geology, Northwest University, Xi’an 710069, China
 show all
Pages 3350-3356 | Received 04 Dec 2007, Accepted 11 Jan 2008, Published online: 13 Oct 2008
 
Sample our Engineering & Technology journals, sign in here to start your access, latest two full volumes FREE to you for 14 days

Abstract

Two uranyl complexes, UO2(p-C7H4O2Br)2(H2O) and UO2(m-C7H4O2Br)2, are synthesized by hydrothermal method and their structures determined by single-crystal X-ray diffraction. UO2(p-C7H4O2Br)2(H2O): R = 0.0606, monoclinic, space group P2(1)/c, with a =19.8400(12) Å, b = 8.8081(5) Å, c = 10.0914(6) Å, α = 90°, β = 92.687(2)°, γ = 90°, Z = 4, has a chair configuration with two cations. UO2(m-C7H4O2Br)2: R = 0.0333, monoclinic, space group P2(1)/c, with a = 5.1084(7) Å, b = 17.642(3) Å, c = 9.0716(13) Å, α = 90°, β = 94.063(2)°, γ = 90(2)°, Z = 2, forms a 1D chain with the ligand (m-bromobenzoic acid) taking the bridging mode.

Acknowledgements

The authors thank the National Basic Research Program of China (the 973 Program, No. 2003CB214606), National Natural Science Foundation of China (No. 20671076), the Program for Changjiang Scholars and Innovative Research Team in University PCSIRT (IRT 0559), the Key Laboratory Research and Establish Program of Shaanxi Education Section, China (No. 03JS006), and the Special Foundation of Shaanxi Education Section, China (No. 04JK143) for their financial support of this work.

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Order Reprints Request Corporate Permissions

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

Request Academic Permissions

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.

Related Research Data

CCDC 661706: Experimental Crystal Structure Determination
Source: Cambridge Crystallographic Data Centre
High-temperature, high-pressure hydrothermal synthesis, crystal structure, and solid-state NMR spectroscopy of Cs2(UO2)(Si2O6) and variable-temperature powder X-ray diffraction study of the hydrate phase Cs2(UO2)(Si2O6) x 0.5H2O.
Source: American Chemical Society (ACS)
Synthesis, thermogravimetry and X-ray analysis of uranyl benzoate and butyrate derivatives
Source: Elsevier BV
Extraction of uranium by amine, amide and benzamide grafted covalently on silica gel
Source: Springer Science and Business Media LLC
CCDC 600949: Experimental Crystal Structure Determination
Source: Cambridge Crystallographic Data Centre
Distorted equatorial coordination environments and weakening of U=O bonds in uranyl complexes containing NCN and NPN ligands.
Source: American Chemical Society (ACS)
UO22+-humate interactions in soft, acid, humate-rich waters
Source: Elsevier BV
Hydrothermal Synthesis and Characterization of [(UO2)2F8(H2O)2Zn2(4,4‘-bpy)2]·(4,4‘-bpy), a Mixed-Metal Uranyl Aquofluoride with a Pillared Layer Structure
Source: (:unav)
Hydrothermal synthesis and crystal structures of new uranyl oxalate hydroxides: α- and β-[(UO2)2(C2O4)(OH)2(H2O)2] and [(UO2)2(C2O4)(OH)2(H2O)2]·H2O
Source: Elsevier BV
[(CH3)4N][(C5H5NH)0.8((CH3)3NH)0.2]U2Si9O23F4 (USH-8): an organically templated open-framework uranium silicate.
Source: (:unav)
Topological Evolution in Uranyl Dicarboxylates: Synthesis and Structures of One-Dimensional UO2(C6H8O4)(H2O)2 and Three-Dimensional UO2(C6H8O4)
Source: (:unav)
Variability of structural motifs in the crystal structure of U(VI) complexes with p-methoxybenzoic acid
Source: Royal Society of Chemistry (RSC)
Synthesis and structure of dimeric complexes of U(VI) and Np(VI) with isophthalic acid anions, {AnO 2 [C 6 H 4 (COO)(COOH)] 2 (H 2 O)} 2
Source: Pleiades Publishing Ltd
Crystal structure and properties of complex [Eu(m-BrBA)3(H2O)(phen)]2
Source: Elsevier BV

Linking provided by 

Related research

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.