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Journal of Coordination Chemistry Volume 62, 2009 - Issue 3
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Original Articles

Crystal structure and electrochemistry of a 2-D polymer with a nano-hole

Yan Xu Department of Chemistry, Zhengzhou University, Zhengzhou, 450052, ChinaCorrespondence[email protected]
,
Chunling Ran Department of Chemistry, Zhengzhou University, Zhengzhou, 450052, China
,
Limin Zhu Department of Chemistry, Zhengzhou University, Zhengzhou, 450052, China
&
Yaoting Fan Department of Chemistry, Zhengzhou University, Zhengzhou, 450052, China
Pages 410-416 | Received 08 Mar 2008, Accepted 23 Apr 2008, Published online: 10 Dec 2009
 
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Abstract

A structure with a nano-hole containing coordination polymer was obtained. X-ray determination shows that it belongs to monoclinic system P 21/n space group, with a = 1.09543(12) nm, b = 1.61279(18) nm, c = 1.43874(16) nm, β = 92.8260(10)° and final R indices R = 0.0523 and Rw = 0.1440. It is a uniform zigzag chain with four Zn atoms, two 4,4′-bipyridines and two ferrocenylcarboxylates forming a macrocyclic.

Acknowledgements

We thank Luoyang Normal College for the diffraction measurements and Henan Province Natural Science Foundation (No. 0611021400).

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