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Journal of Coordination Chemistry Volume 62, 2009 - Issue 3
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Original Articles

Synthesis, structure and luminescent properties of zinc(II) and Hg(II) complexes with substituted 1,10-phenanthroline

Xiaoming Liu State Key Laboratory of Supramolecular Structure and Materials, School of Chemistry, Jilin University, Changchun 130012, P. R. China; State Key Laboratory on Integrated Optoelectronics, College of Electronic Science and Engineering, Jilin University, Changchun 130012, P. R. China
,
Hong Xia State Key Laboratory on Integrated Optoelectronics, College of Electronic Science and Engineering, Jilin University, Changchun 130012, P. R. China
,
Wei Gao State Key Laboratory of Supramolecular Structure and Materials, School of Chemistry, Jilin University, Changchun 130012, P. R. China
,
Bo Gao State Key Laboratory of Supramolecular Structure and Materials, School of Chemistry, Jilin University, Changchun 130012, P. R. China
&
Ying Mu State Key Laboratory of Supramolecular Structure and Materials, School of Chemistry, Jilin University, Changchun 130012, P. R. ChinaCorrespondence[email protected]
Pages 400-409 | Received 19 Feb 2008, Accepted 23 Apr 2008, Published online: 10 Dec 2009
 
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Abstract

Two d10 group 12 metal complexes, 2-(2-methoxyphenyl)-1,10-phenanthroline zinc dichloride (2a) and 2-(2-methoxyphenyl)-1,10-phenanthroline mercury dichloride (2b) were synthesized and characterized by IR, 1H and 13C NMR as well as elemental analysis. Structure of 2b in the solid state was determined by single-crystal X-ray crystallography, revealing that 2b is four-coordinate in a distorted tetrahedral geometry with the methoxy group uncoordinated. Luminescent properties of 2a and 2b in solution and the solid state were studied.

Acknowledgements

This work was supported by the National Natural Science Foundation of China (No. 20674024) and Ministry of Science and Technology of China (No. 2002CB6134003). One of the authors (Dr X. Liu) is grateful for the financial support from Jilin University.

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