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Journal of Coordination Chemistry Volume 62, 2009 - Issue 7
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Original Articles

Synthesis, crystal structure and magnetism of a two-dimensional Ni(II) coordination polymer with thiocyanate anion and dehydrogen-1,10-phenanthrolin-2-ol as bridging ligands

Jing-Min Shi Department of Chemistry, Shandong Normal University, Jinan 250014, P.R. ChinaCorrespondence[email protected]
,
Qi-Sheng Liu Department of Chemistry, Shandong Normal University, Jinan 250014, P.R. China
&
Wei Shi Department of Chemistry, Nankai University, Tianjin 30071, P.R. China
Pages 1121-1126 | Received 05 Jun 2008, Accepted 21 Jul 2008, Published online: 29 Jul 2010
 
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Abstract

A two-dimensional coordination polymer [Ni(μ1,3-SCN)(μ-Pheno)(CH3OH)] n (where Pheno = dehydrogen-1,10-phenanthrolin-2-ol) has been synthesized and its crystal structure determined by X-ray crystallography. Adjacent Ni(II) ions are coordinated by μ1,3-SCN− and μ-Pheno alternately forming a two-dimensional sheet structure. The fitting of the variable-temperature magnetic susceptibilities with a binuclear nickel(II) formula reveals that there is an anti-ferromagnetic interaction between the bridging Ni(II) ions with the magnetic coupling constant 2J = −0.67 cm−1.

Acknowledgment

This work was supported by the National Nature Science Foundation of China (No. 20271043).

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