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Journal of Coordination Chemistry Volume 62, 2009 - Issue 24
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Original Articles

Synthesis, crystal structure, and properties of a new zinc coordination polymer [Zn(PMP)2Cl]n

Rui-Bo Xu Department of Chemical Engineering, Huaihai Institute of Technology, Lianyungang 222005, P.R. China; Laboratory of Soft Chemistry and Functional Materials, Nanjing University of Science and Technology (Ministry of Education), Nanjing 210094, P.R. China
,
Xing-You Xu Huaiyin Institute of Technology, Huaian 223003, P.R. ChinaCorrespondence[email protected]
,
Yu-He Yin School of Chemistry and Life Science, Changchun University of Technology, Changchun 130012, P.R. China
,
Ming-Yan Wang Department of Chemical Engineering, Huaihai Institute of Technology, Lianyungang 222005, P.R. China
,
Xu-Jie Yang Laboratory of Soft Chemistry and Functional Materials, Nanjing University of Science and Technology (Ministry of Education), Nanjing 210094, P.R. China
,
Qian-Qian Xu Department of Chemical Engineering, Huaihai Institute of Technology, Lianyungang 222005, P.R. China
&
Li-Ping Ma Department of Chemical Engineering, Huaihai Institute of Technology, Lianyungang 222005, P.R. China
 show all
Pages 3905-3912 | Received 05 Feb 2009, Accepted 10 Jun 2009, Published online: 22 Sep 2010
 
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Abstract

A new coordination polymer [Zn(PMP)2Cl] n (PMP = 1-phenyl-3-methyl-5-pyrazolone) has been prepared by the reaction of zinc chloride and PMP, and characterized by elemental analysis, IR, UV, and fluorescence spectra, TG/DTA, and electrochemical analysis. Single crystal X-ray diffraction revealed that the complex is monoclinic, space group P 2(1)/n, with a = 10.850(17), b = 17.578(2), c = 10.997(18) Å, β = 104.999(3)°, V = 2025.8(5) Å3, Z = 4, Dc = 1.470 mg m−3, F(000) = 920, goodness-of-fit = 0.905, and R 1 = 0.0441. The complex is a 1-D coordination polymer, and the coordination geometry of Zn(II) is a distorted tetrahedron.

Acknowledgment

This work was supported by the Major Project for Fundamental Research of Jiangsu Provincial Educational Committee (07KJA150011) and the Qing Lan Project of Jiangsu Province.

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