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Journal of Coordination Chemistry Volume 63, 2010 - Issue 7
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Original Articles

Mercury(II) complexes of pyrrolidinedithiocarbamate, crystal structure of bis{[μ2-(pyrrolidinedithiocarbamato-S,S ′)(pyrrolidinedithiocarbamato-S,S ′)mercury(II)]}

Muhammad Altaf Institute of Physics, University of Neuchâtel, CH-2009 Neuchâtel, Switzerland
,
Helen Stoeckli-Evans Institute of Physics, University of Neuchâtel, CH-2009 Neuchâtel, Switzerland
,
Syeda Shahzadi Batool Department of Chemistry, University of Engineering and Technology, Lahore 54890, Pakistan
,
Anvarhusein A. Isab Department of Chemistry, King Fahd University of Petroleum and Minerals, Dhahran 31261, Saudi Arabia
,
Saeed Ahmad Department of Chemistry, University of Engineering and Technology, Lahore 54890, PakistanCorrespondence[email protected]
,
Muhammad Saleem PAEC, P.O. Box 1114, Islamabad GPO 44000, Pakistan
,
Shafique Ahmad Awan PAEC, P.O. Box 1114, Islamabad GPO 44000, Pakistan
&
Muhammad Ashraf Shaheen Department of Chemistry, University of Sargodha, Sargodha, Pakistan
 show all
Pages 1176-1185 | Received 16 Sep 2009, Accepted 23 Dec 2009, Published online: 13 Apr 2010
 
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Abstract

Mercury(II) complexes of pyrrolidinedithiocarbamate (PDTC) having the general formula [Hg(PDTC)X] (X = Cl−, SCN−, and CN−) and [Hg(PDTC)2] have been prepared and characterized by elemental analysis, IR, and NMR. The crystal structure of [Hg(PDTC)2] has also been determined by X-ray crystallography, showing that the complex is a centrosymmetric dimer, [Hg2(PDTC)4] (bis[µ2-(pyrrolidinedithiocarbamato-S,S′)(pyrrolidinedithiocarbamato-S,S′)mercury(II)]) (1). The solid-state structure of 1 contains two crystallographically equivalent Hg(II) centers in a distorted tetrahedron.

Acknowledgment

Financial support from Pakistan Council for Science and Technology, Islamabad is gratefully acknowledged.

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