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Journal of Coordination Chemistry Volume 63, 2010 - Issue 11
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Original Articles

A new linear-chain complex based on heptamolybdates with {Ce(H2O)5} linkers

Youzhi Fu Department of Chemistry, Baicheng Teacher's College, Baicheng 137000, P.R. ChinaCorrespondence[email protected]
Pages 1856-1864 | Received 18 Dec 2009, Accepted 11 Mar 2010, Published online: 25 Jun 2010
 
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Abstract

A new linear-chain structure based on heptamolybdates with the linkage of {Ce(H2O)5} units, (C6H13N4)2(H3O)[Ce(H2O)5Mo7O24] · 4H2O (1) has been synthesized and characterized by single crystal X-ray diffraction, IR spectroscopy, elemental analysis, and thermogravimetric analysis. Magnetic studies show strong spin–orbital coupling interactions and/or antiferromagnetic interactions within Ce(III) centers.

Acknowledgments

This work was financially supported by the National Natural Science Foundation of China (grants 20373009).

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