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Journal of Coordination Chemistry Volume 64, 2011 - Issue 4
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Original Articles

A 2-D tetrazole-based Zn(II) coordination polymer: crystal structure, dielectric constant, and luminescence

Li-Zhuang Chen School of Material Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, P.R. ChinaCorrespondence[email protected]
,
Jun Zou School of Material Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, P.R. China
,
Yan-Min Gao School of Material Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, P.R. China
,
Sheng Wan School of Material Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, P.R. China
&
Mei-Na Huang School of Material Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, P.R. China
Pages 715-724 | Received 12 May 2010, Accepted 03 Dec 2010, Published online: 18 Feb 2011
 
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Abstract

A tetrazole-based Zn(II) coordination polymer, [Zn(TMPT)2] n (1) (TMPT = 5-(4-((1H-1,2,4-triazol-1-yl)methyl)phenyl)-2H-tetrazole), was synthesized by in situ reaction of 4-((1H-1,2,4-triazol-1-yl)methyl)benzonitrile, Zn(NO3)2 · 6H2O, and NaN3 under hydrothermal conditions and structurally characterized by single-crystal X-ray diffraction. Complex 1 contains π–π stacking interactions between tetrazole rings and phenyl rings of the 2-D ordered layered structural framework, which contribute to the dielectric response. In addition, 1 was demonstrated to display strong blue fluorescence emissions in the solid state at room temperature.

Acknowledgments

This work was financially supported by the National Natural Science Foundation of China and Jiangsu province NSF (BK2008029).

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