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Journal of Coordination Chemistry Volume 64, 2011 - Issue 6
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Original Articles

Synthesis, characterization, and magnetic properties of a coordination polymer of nickel: poly[μ4-dicyanamide-(2,9-dimethyl-1,10-phenanthroline-κ2N,N′)nickel(II)]

Tian-Fu Liu Department of Chemistry, Beijing Institute of Technology, Beijing 100081, P.R. China; Key Laboratory of Cluster Science, Ministry of Education of China, Beijing Institute of Technology, Beijing 100081, P.R. ChinaCorrespondence[email protected]
,
Zhongming Bao School of Foreign Languages, Beijing Institute of Technology, Beijing 100081, P.R. China
&
Ling-Ling Li Department of Chemistry, Beijing Institute of Technology, Beijing 100081, P.R. China; Key Laboratory of Cluster Science, Ministry of Education of China, Beijing Institute of Technology, Beijing 100081, P.R. China
Pages 1063-1068 | Received 01 Sep 2010, Accepted 23 Dec 2010, Published online: 09 Mar 2011
 
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Abstract

A new coordination polymer of Ni2+, (dicyanamide, herein denoted dca) and 2,9-dimethyl-1,10-phenanthroline (dmphen), has been synthesized, structurally and magnetically characterized. {[Ni2(dmphen)2[µ-dca]4} n (1), which crystallizes in the monoclinic space group P21 /n, has a 2-D network that consists of double-bridged [Ni2(dca)2(dmphen)2]2+ “dimers” connected via single-bridging dca ligands and exhibits a typical (6, 3) topological network. Each NiN6 octahedron comprises a bidentate dmphen and four µ1,5-bridging dca anions. Magnetic susceptibility measurements indicate antiferromagnetic interactions between Ni(II) ions via the dca bridge.

Acknowledgments

We are grateful for the Natural Science Foundation Council of China (NSFC) (grant No. 20401003) and 111 Project (B07012) for the financial support.

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