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Journal of Coordination Chemistry Volume 64, 2011 - Issue 10
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Original Articles

Syntheses and structural characterization of two metal-organic frameworks from tripodal and dipodal ligands

Jian-Qiang Liu Guangdong Medical College, School of Pharmacy, Dongguan 523808, P.R. ChinaCorrespondence[email protected]
Pages 1807-1814 | Received 26 Jan 2011, Accepted 24 Mar 2011, Published online: 19 May 2011
 
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Abstract

Two isomorphic metal–organic frameworks, {[M3(nbtb)2(bpe)3(H2O)2] · 2H2O} n (M = Co for (1) and Ni for (2)), have been synthesized by the combination of an extended linker 1,2-bi(4-pyridyl)ethene(bpe) and tripodal tecton 5-nitro-1,2,3-benzenetricarboxylic acid. Single-crystal X-ray diffraction studies indicate that 1 and 2 are (4, 5)-connected motifs containing (42 · 67 · 8) (42 · 67 · 8) (64 · 82) (42 · 64) topologies. The magnetic behavior of 1 exhibits weak antiferromagnetic interaction between metal centers.

Acknowledgment

This work was supported by the Guangdong Medical College.

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