Advanced search
Publication Cover
Journal of Coordination Chemistry Volume 64, 2011 - Issue 11
Submit an article Journal homepage
101
Views
4
CrossRef citations to date
0
Altmetric
Original Articles

Synthesis, structure, and magnetism of a new 2-D copper(II) complex based on two different dicarboxylates

Yu Pang Key Laboratory of Polyoxometalate Science of Ministry of Education, Department of Chemistry, Northeast Normal University, Changchun, Jilin 130024, China
,
Dan Tian Key Laboratory of Polyoxometalate Science of Ministry of Education, Department of Chemistry, Northeast Normal University, Changchun, Jilin 130024, China
,
Yuhui Luo Key Laboratory of Polyoxometalate Science of Ministry of Education, Department of Chemistry, Northeast Normal University, Changchun, Jilin 130024, China
,
Xiaofei Zhu Key Laboratory of Polyoxometalate Science of Ministry of Education, Department of Chemistry, Northeast Normal University, Changchun, Jilin 130024, China
&
Hong Zhang Key Laboratory of Polyoxometalate Science of Ministry of Education, Department of Chemistry, Northeast Normal University, Changchun, Jilin 130024, ChinaCorrespondence[email protected]
Pages 2002-2009 | Received 16 Jan 2011, Accepted 05 Apr 2011, Published online: 27 May 2011
 
Sample our Physical Sciences journals, sign in here to start your FREE access for 14 days

Abstract

A new 2-D copper(II) complex, [Cu2L1L2(H2O)2] · 3H2O (1) (H2L1 = 2,4-dibenzoylisophthalic acid and H2L2 = 2,5-dibenzoylterephthalic acid), has been synthesized by the reaction of copper(II) nitrate and two different dicarboxylates under hydrothermal conditions. This complex is characterized structurally by elemental analysis, IR spectra, thermogravimetric analysis, and X-ray diffraction. Complex 1 has a 2-D layer structure with (44 · 62) topology. The adjacent 2-D layers are further extended via O–H ··· O hydrogen bonds into a 3-D supramolecular structure; 1 shows antiferromagnetic interactions.

Acknowledgments

We gratefully acknowledge financial support by the NSF of China (nos. 21071027, 20771023), the China High-Tech Development 863 Program (no. 2007AA03Z218), and analysis and testing foundation of Northeast Normal University.

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Order Reprints Request Corporate Permissions

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

Request Academic Permissions

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.

Related Research Data

Poly[[tetra‐μ2‐aqua‐diaqua‐μ2‐2,5‐dibenzoyl­terephthalato­dipotassium(I)] dihydrate]
Source: (:unav)
Preparation, structure, and magnetic properties of dimeric copper(II) tribromoacetate adducts. Influence of the substituent R on the magnetic behavior of the series of dimers [Cu(O2CR)2L[2 (R=H, CH3, CF3, CCl3, CBr3)
Source: American Chemical Society (ACS)
Carboxylate-bridged copper(II) complexes: synthesis, crystal structures, and superoxide dismutase activity
Source: Informa UK Limited
Syntheses and crystal structures of two Co(II) coordination polymers based on 4,6-bis(4-methylbenzoyl)isophthalic acid and 4,4′-bipyridine
Source: Informa UK Limited
A binuclear Cu(II) complex of a Schiff-base type polyhydroxyl ligand with asymmetrical phenoxo and methoxo bridges: crystal structure and magnetic properties
Source: Informa UK Limited
Hydrothermal Assembly of Two New 3D Zinc(II) pcu Nets
Source: Wiley
Two cobalt(II) coordination polymers based on carboxylate ligand: Preparation, crystal structures and magnetic properties
Source: Elsevier BV
Template-Directed Architectural Isomerism of Open Molecular Frameworks: Engineering of Crystalline Clathrates
Source: American Chemical Society (ACS)
Dicarboxylate anion-dependent assembly of Ni(II) coordination polymers with 4,4′-dipyridyl sulfide
Source: Royal Society of Chemistry (RSC)
Structure of the dibenzoylphthalic acids obtained by condensation of pyromellitic dianhydride with benzene
Source: Springer Science and Business Media LLC
Hydrothermal Syntheses, Crystal Structures, and Properties of a Novel Class of 3,3‘,4,4‘-Benzophenone-tetracarboxylate (BPTC) Polymers
Source: American Chemical Society (ACS)
Inorganic−Organic Hybrid Compounds: Synthesis and Structures of New Metal Organic Polymers Synthesized in the Presence of Mixed Dicarboxylates
Source: Wiley
Three new polynuclear tetracarboxylato-bridged copper(II) complexes: Syntheses, X-ray structure and magnetic properties
Source: Elsevier BV
Enhancing H2 Uptake by “Close‐Packing” Alignment of Open Copper Sites in Metal–Organic Frameworks
Source: (:unav)
Hydrothermal syntheses, characterizations, and luminescence of three new complexes based on 4,6-dibenzoylisophthalic acid
Source: Informa UK Limited
Coordination polymers constructed from 2-(2-thienyl)imidazo[4,5-f]1,10-phenanthroline and isophthalate: synthesis, characterization and luminescent property
Source: (:unav)
A metal-organic framework with a hierarchical system of pores and tetrahedral building blocks
Source: Wiley
Design, Synthesis, Structure, and Gas (N2, Ar, CO2, CH4, and H2) Sorption Properties of Porous Metal-Organic Tetrahedral and Heterocuboidal Polyhedra
Source: (:unav)
Bis(triaquasodium) 2,5-dibenzoylterephthalate tetrahydrate
Source: International Union of Crystallography (IUCr)
Enhancing H2 Uptake by “Close‐Packing” Alignment of Open Copper Sites in Metal–Organic Frameworks
Source: (:unav)
A Crystalline Mesoporous Coordination Copolymer with High Microporosity
Source: Wiley
Unique (3,13)-Connected Coordination Framework Based on Pentacobalt Clusters Constructed from the (3,12)-Connected Analogue and 4,4′-Bipyridyl Spacer: Structural and Magnetic Aspects
Source: American Chemical Society (ACS)
1D, 2D, and 3D Metal−Organic Frameworks Based on Bis(imidazole) Ligands and Polycarboxylates: Syntheses, Structures, and Photoluminescent Properties
Source: American Chemical Society (ACS)
Synthesis, crystal structure and properties of cobalt(II) and nickel(II) coordination polymers supported by functionalized dicarboxylate ligands
Source: Elsevier BV
The Ln–Cu(II)–Hpic–H2BDC system showing interesting production variety upon different reaction conditions: hydrothermal synthesis, structures, thermostability, and magnetism
Source: (:unav)
Syntheses and characterizations of copper(II) polymeric complexes constructed from 1,2,4,5-benzenetetracarboxylic acid.
Source: American Chemical Society (ACS)
2,5‐Dibenzoylterephthalic acid dihydrate
Source: International Union of Crystallography (IUCr)
A new 3D coordination framework with helical chains in mixed ligands system: Preparation, crystal structure and magnetic property
Source: Elsevier BV
A Crystalline Mesoporous Coordination Copolymer with High Microporosity
Source: Wiley
A novel class of interpenetrated 3-D network of a dimeric cupric-tetracarboxylate unit
Source: Royal Society of Chemistry (RSC)
CCDC 796814: Experimental Crystal Structure Determination
Source: Cambridge Crystallographic Data Centre

Linking provided by 

Related research

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.