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Journal of Coordination Chemistry Volume 64, 2011 - Issue 12
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Original Articles

Structural study on a sulfido-bridged dinuclear organotin(IV) complex with weak Sn ··· Sn bonding

Neetu Singh Department of Chemistry, Faculty of Science, Banaras Hindu University, Varanasi, Uttar Pradesh, India
&
Subrato Bhattacharya Department of Chemistry, Faculty of Science, Banaras Hindu University, Varanasi, Uttar Pradesh, IndiaCorrespondence[email protected]
Pages 2170-2177 | Received 03 Feb 2011, Accepted 04 May 2011, Published online: 22 Jun 2011
 
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Abstract

A dinuclear anionic complex, Bu4N[Me2SnCl(S)ClSnMe2Br], has been synthesized in chloroform solution by reacting (Me2SnS)3, Me2SnCl2, and Bu4NBr. Attempts to isolate the anionic complex using tetramethylammonium cation were unsuccessful. The anion possesses two five-coordinate tin(IV) units bridged by sulfide and bromide. X-ray diffraction study revealed the possibility of a weak Sn–Sn bond in the complex. Theoretical (DFT) studies have been carried out to analyze the nature of metal–metal interaction in the complex.

Acknowledgment

Financial support from the Council of Scientific and Industrial Research, India, is gratefully acknowledged.

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