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Journal of Coordination Chemistry Volume 64, 2011 - Issue 14
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Original Articles

Synthesis and characterization of polymeric triphenyltin and cyclotetrameric tricyclohexyltin 2-(1H-imidazol-1-yl)acetates

Xian-Xue Gan Department of Chemistry and Chemical Engineering, Yibin University, Yibin, Sichuan 644007, P.R. China
&
Liang-Fu Tang Department of Chemistry, State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, P.R. ChinaCorrespondence[email protected]
Pages 2458-2465 | Received 14 Mar 2011, Accepted 06 Jun 2011, Published online: 13 Jul 2011
 
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Abstract

The reaction of 2-(1H-imidazol-1-yl)acetic acid with (Ph3Sn)2O or Cy3SnOH (Cy = cyclohexyl) yields triphenyltin 2-(1H-imidazol-1-yl)acetate (1) and tricyclohexyltin 2-(1H-imidazol-1-yl)acetate (2), respectively. 2-(1H-imidazol-1-yl)acetates in these two complexes show remarkably different coordination modes. Complex 1 forms a polymeric chain structure through intermolecular Sn–N interactions, while 2 displays a 28-membered macrocyclic tetranuclear structure by the assembly of Sn–N coordination bonds.

Acknowledgments

We thank the National Natural Science Foundation of China (No. 20721062) for financial support.

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