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Journal of Coordination Chemistry Volume 64, 2011 - Issue 14
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Original Articles

Two 3-D metal-organic frameworks constructed by 2-methyl or 2-ethyl imidazole dicarboxylates

Nan Chen Department of Chemistry, Zhengzhou University, Zhengzhou, Henan 450052, P.R. China
,
Jun Zhang Department of Chemistry, Zhengzhou University, Zhengzhou, Henan 450052, P.R. China
,
Yong-Chao Gao Department of Chemistry, Zhengzhou University, Zhengzhou, Henan 450052, P.R. China
,
Ze-Li Yang Department of Chemistry, Zhengzhou University, Zhengzhou, Henan 450052, P.R. China
,
Hui-Jie Lu Department of Chemistry, Zhengzhou University, Zhengzhou, Henan 450052, P.R. China
&
Gang Li Department of Chemistry, Zhengzhou University, Zhengzhou, Henan 450052, P.R. ChinaCorrespondence[email protected]
Pages 2554-2564 | Received 01 Apr 2011, Accepted 06 Jun 2011, Published online: 26 Jul 2011
 
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Abstract

Two polymeric frameworks, [Zn5(MIDC)2(HMIDC)2(phen)5] n (1) (H3MIDC = 2-methyl-1H-imidazole-4,5-dicarboxylic acid, phen = 1,10-phenanthroline) and {[Ca2(HEIDC)2(H2O)] · H2O} n (2) (H3EIDC = 2-ethyl-1H-imidazole-4,5-dicarboxylic acid), have been solvothermally synthesized and structurally characterized by single-crystal X-ray diffraction. Compound 1 exhibits a 3-D structure constructed from 2-D layer motifs joined by µ 2-HMIDC2− or µ 3-MIDC3− ligands. Compound 2 also presents a 3-D framework, generated from 1-D chains linked by HEIDC2− ligands by two different µ5-modes. The thermal and solid-state photoluminescence properties of both the complexes have been determined.

Acknowledgments

We gratefully acknowledge the financial support by the National Natural Science Foundation of China (21071127, 20501017 and J0830412), and Program for New Century Excellent Talents in University and the Natural Science Foundation of Henan Education Department (2009A150028 and 2011A150029).

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