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Journal of Coordination Chemistry Volume 64, 2011 - Issue 15
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Original Articles

Synthesis and crystal structure of 2-D silver coordination polymers containing aminopyrazine

Hui-An Tsai Department of Material and Fiber, Graduate School of Materials Applied Technology, Nanya Institute of Technology, Jhongli, Taiwan, ROC; R&D Center for Membrane Technology, Chung-Yuan Christian University, Jhongli, Taiwan, ROC
,
Maw-Cherng Suen Department of Material and Fiber, Graduate School of Materials Applied Technology, Nanya Institute of Technology, Jhongli, Taiwan, ROCCorrespondence[email protected]
,
Pin-Ning Wang Department of Material and Fiber, Graduate School of Materials Applied Technology, Nanya Institute of Technology, Jhongli, Taiwan, ROC
,
Yi-Fen Hsu Department of Chemistry, Chung-Yuan University, Jhongli, Taiwan, ROC
&
Ju-Chun Wang Department of Chemistry, Soochow University, Taipei, Taiwan, ROC
Pages 2658-2666 | Received 06 Aug 2010, Accepted 20 Jun 2011, Published online: 28 Jul 2011
 
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Abstract

Two supramolecules of Ag(I), [Ag(NO3)(APZ)] n (1) and {[Ag(APZ)2][CF3COO] · H2O} n (2) (APZ = aminopyrazine) have been prepared by self-assembly of Ag(I) salts with APZ in MeOH/H2O. EA, IR, and TGA spectra have been recorded and the complexes have been structurally characterized by X-ray crystallography, confirming that 1 and 2 are 2-D pleated rectangular grid coordination polymers. The in 1 is coordinated to Ag+, bidentate, and μ2,η1-, while CF3COO− in 2 is not coordinated. Ag ··· O interactions, hydrogen bonds, and π ··· π stacking interactions support the supramolecular structures.

Acknowledgments

We are grateful to the Nanya Institute of Technology and the National Science Council of the Republic of China for support.

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