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Journal of Coordination Chemistry Volume 64, 2011 - Issue 20
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Original Articles

3-D Coordination polymer containing a 1-D tunnel filled with 4,4′-bpy: synthesis, crystal structure, and characterization

Fan Guang College of Chemistry and Material Science, Shaanxi Normal University, Xi’an, Shaanxi 710062, China; College of Chemistry and Chemical Engineering, Xianyang Normal University, Xianyang, Shaanxi 712000, China
,
Yang Zu-Pei College of Chemistry and Material Science, Shaanxi Normal University, Xi’an, Shaanxi 710062, ChinaCorrespondence[email protected]
,
Zhang Yin-Li College of Chemistry and Chemical Engineering, Xianyang Normal University, Xianyang, Shaanxi 712000, China
,
Sun Jia-Juan College of Chemistry and Chemical Engineering, Xianyang Normal University, Xianyang, Shaanxi 712000, China
,
Zheng Min-Yan College of Chemistry and Chemical Engineering, Xianyang Normal University, Xianyang, Shaanxi 712000, China
&
Yu Zhan-Jiang College of Chemistry and Chemical Engineering, Xianyang Normal University, Xianyang, Shaanxi 712000, China
Pages 3475-3481 | Received 20 Mar 2011, Accepted 04 Aug 2011, Published online: 03 Oct 2011
 
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Abstract

A coordination polymer, [Co(2-mpac)2(4,4′-bpy)·(4,4′-bpy)] n (2-mpac: 5-methyl-2-pyrazinecarboxylic acid; 4,4′-bpy: 4,4′-bipyridine), has been synthesized through hydrothermal synthesis and structurally characterized by X-ray single crystal diffraction. Single crystal X-ray diffraction analysis reveals a 3-D network featuring a 1-D tunnel filled with 4,4′-bpy molecules. Elemental analysis, IR, thermogravimetric analysis, and magnetic properties are presented.

Acknowledgments

We gratefully acknowledge the financial support from the Natural Science Foundation of Shaanxi Province (2009JQ2015, 2010JM2009), the Special Research Fund of Education Department of Shaanxi Province (09JK798, 2010JK902), and the Special Research Fund of Xianyang Normal University for Talent Introduction (08XSYK306).

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