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Journal of Coordination Chemistry Volume 64, 2011 - Issue 21
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Original Articles

A new organic–inorganic hybrid based on Mn–salen and decavanadate

Shiwei Lin Key Laboratory of Polyoxometalate Science of Ministry of Education, Department of Chemistry, Northeast Normal University, 130024 Changchun, P.R. China; Department of Chemistry, Changchun Normal University, 130032 Changchun, P.R. China
,
Qiong Wu Key Laboratory of Polyoxometalate Science of Ministry of Education, Department of Chemistry, Northeast Normal University, 130024 Changchun, P.R. China; Department of Chemistry Science & Technology, Kunming University, 650214 Kunming, P.R. China
,
Huaqiao Tan Key Laboratory of Polyoxometalate Science of Ministry of Education, Department of Chemistry, Northeast Normal University, 130024 Changchun, P.R. China
&
Enbo Wang Key Laboratory of Polyoxometalate Science of Ministry of Education, Department of Chemistry, Northeast Normal University, 130024 Changchun, P.R. ChinaCorrespondence[email protected]
Pages 3661-3669 | Received 05 Aug 2011, Accepted 14 Sep 2011, Published online: 24 Oct 2011
 
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Abstract

An organic–inorganic hybrid based on Mn-salen and decavanadate, [NH4]2[Mn(salen)(H2O)2]4[V10O28] · 6H2O (1) (salen = N,N′-ethylene-bis(salicylideneiminate)), has been synthesized by the strategy of secondary building units in mixed methanol–water solution and was structurally characterized by single-crystal X-ray diffraction, elemental analyses, IR, and UV-Vis. The [Mn(salen)(H2O)2]+ cations and water molecules are located in the interspaces among the polyoxoanions [V10O28]6− forming a POM-based supramolecule. Compound 1 is the first example of metal-Schiff-base polyoxovanadates. The photocatalytic analysis, cyclic voltammetry, and electrocatalytic analysis of 1 have been investigated.

Acknowledgments

This work was supported by the National Natural Science Foundation of China (No. 20701005/20701006); the Science and Technology Development Project Foundation of Jilin Province (No. 20060420); the Postdoctoral station Foundation of Ministry of Education (No. 20060200002); the Testing Foundation of Northeast Normal University; the Program for Changjiang Scholars and Innovative Research Team in University; and the Natural Science Foundation of Changchun Normal University.

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