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Journal of Coordination Chemistry Volume 64, 2011 - Issue 21
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Original Articles

A 1-D cyano-bridged coordination polymer, [Ni(NH3)6]2[{Ni(NH3)4}{Re12CS17(CN)6}] · 8H2O: reactivity studies of dodecanuclear rhenium cluster anion [Re12CS17(CN)6]6− in Ni(II)-ammonia system

Yakov M. Gayfulin Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Akad. Lavrentiev prosp., 3, Novosibirsk 630090, Russian Federation
,
Anton I. Smolentsev Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Akad. Lavrentiev prosp., 3, Novosibirsk 630090, Russian FederationCorrespondence[email protected]
&
Yuri V. Mironov Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Akad. Lavrentiev prosp., 3, Novosibirsk 630090, Russian Federation
Pages 3832-3840 | Received 11 Aug 2011, Accepted 29 Sep 2011, Published online: 04 Nov 2011
 
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Abstract

A cyano-bridged coordination polymer, [Ni(NH3)6]2[{Ni(NH3)4}{Re12CS17(CN)6}] · 8H2O, has been synthesized by reaction between concentrated aqueous ammonia solution of NiCl2 and aqueous solution of K6[Re12CS17(CN)6]. The compound has been characterized by single crystal X-ray diffraction, IR-spectroscopy and EDS analysis. The compound adopts 1-D structure, which consists of anionic chains [{Ni(NH3)4}{Re12CS17(CN)6}], discrete cations [Ni(NH3)6]2+ and crystal waters bonded together by hydrogen bonds. The influence of reagent concentrations on composition and structure of the resultant product has also been studied and discussed.

Acknowledgments

This work was supported by the Russian Foundation for Basic Research (project No. 10-03-01040) and by the State Contract No. 02.740.11.0628.

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